Atomic Orbitals
The aim of this chapter is to understand the various bonds acting between atoms and molecules. This is however not possible without some knowledge about the atomic structure. To that end a bit of quantum mechanics is required.
Quantum Mechanical Description
Wave Function and Schrödinger Equation
In quantum mechanics the state of a physical system is determined by its wave function $\psi$ which in turn is the solution of the Schrödinger equation for this system.
Atomic Orbitals and Quantum Numbers
For a single electron in an atom such a particular state is called orbital and specified by three quantum numbers:[1][2]
- The principal (energy) quantum number $n = 1,2,\dots$
- The angular momentum quantum number $l = 0, 1, \dots, n-1$. For historical reasons the different numbers are denoted by letters, namely $0 \rightarrow \text{s}$, $1 \rightarrow \text{p}$, $2 \rightarrow \text{d}$ and $3 \rightarrow \text{f}$)
- The magnetic quantum number ${m = -l, -(l-1), \dots, l-1, l}$
In addition to these orbital quantum numbers there is another so-called spin quantum number ${s = \pm \frac{1}{2}}$ which can be thought of as an intrinsic angular momentum. This will become relevant later.
Probability Density
One can now calculate the probability densitiy of finding the electron in a specific location for a certain orbital. It is the squared value ${\left| \psi (x) \right|^2}$ of the wave function at this particular location.[3] One can visualise the orbital by creating three dimensional figures showing the areas with a high detection probability densitiy.[4]
This is done in the following for s-, p- and d-orbitals.[5] In the notation (1s, 2p, 3d) the numbers represent the principal quantum number $n$ and the letters the angular momentum quantum numbers $l$. The different colors mark different signs of the wave function.
1s-Orbital
2p-Orbitals
3d-Orbitals
References
[1] | Atomic Structure and Periodicity The Royal Society of Chemistry 2007 (ch. 2.1.2 and 2.1.4) |
[2] | Gerthsen Physik Springer 2010 (p. 822) |
[3] | Gerthsen Physik Springer 2010 (p. 701) |
[4] | Atomic Structure and Periodicity The Royal Society of Chemistry 2007 (ch. 2.1.2) |
[5] | Atomic Structure and Periodicity The Royal Society of Chemistry 2007 (p. 31 ff.) |